Category: sygmlvwnhhlu

La fondation Nicolas Hulot quitte le Grenelle de lenvironnement

first_imgLa fondation Nicolas Hulot quitte le Grenelle de l’environnementFrance – Au lendemain de l’annonce du report de la taxe carbone, la fondation Nicolas Hulot a décidé de suspendre sa participation aux groupes de travail chargés de travailler sur le projet de loi du second Grenelle de l’environnement et de la mer. Furieux de la décision du gouvernement, qui préfère attendre la mise en place d’une taxe européenne pour instaurer la contribution climat-énergie en France, Nicolas Hulot a annoncé que sa fondation ne participerait pas aux prochains travaux du Grenelle de l’environnement.”L’abandon pur et simple de la taxe carbone, alors qu’un processus de concertation était en cours, est symptomatique d’un net recul de la classe politique qui, à droite comme à gauche, n’a pas pris la mesure des enjeux écologiques, et les considère essentiellement comme une variable d’ajustement politique” estime la fondation, quand le ministre de l’Environnement Jean-Louis Borloo assure que la décision de Nicolas Hulot n’est rien d’autre qu’un “moment d’énervement”.Bruno Le Maire, ministre de l’Agriculture, appelle lui aussi l’initiateur du pacte écologique signé par Nicolas Sarkozy lors de la dernière campagne présidentielle à revenir à la raison. “J’ai eu l’occasion de rencontrer Nicolas Hulot à plusieurs reprises, et sa participation est utile […]. On a toujours intérêt à écouter les avis des organisations non gouvernementales, des associations écologistes” a-t-il estimé sur Europe 1.La suspension de la participation de la fondation au Grenelle a suscité de très nombreuses autres réactions. Alain Juppé a ainsi assuré comprendre la réaction de Nicolas Hulot face au regain de l’écolo-scepticisme “alors que les problèmes sont toujours devant nous”. De son côté, Jean-François Copé, président du groupe UMP à l’Assemblée, a affirmé regretter la décision de l’écologiste, soulignant que “ce serait une erreur énorme de réduire” le Grenelle de l’environnement à la seule taxe carbone.Le 30 mars 2010 à 16:45 • Emmanuel Perrinlast_img read more

John Cena Big Cass and Enzo Amore vs The Club and Becky

first_img Vin Diesel and John Cena share ‘intense’ scene Now Playing Up Next Adam Martin RELATED ARTICLESMORE FROM AUTHOR Comments are closed. Enzo Amore Former WWE star Big Cass reportedly has incident at WrestlePro Event in New Jersey 1 COMMENT Now Playing Up Next Now Playing Up Next WWE Lists The Shields Top 10 Wins Now Playing Up Next WWE Wrestler Enzo Amore Kicked Off Flight Pinterest July 5, 2016 at 1:03 am Joey Janela comments on backstage incident with Big Cass at WrestlePro Event I really hope The (Bullet) Club wins at BattleGround. Twitter Videos Articles Now Playing Up Next Big Cass WWE Superstar John Cena announced as part of cast for Suicide Squad Sequel Videos Articles John Cena, Big Cass and Enzo Amore vs. The Club in a six man tag team match and Becky Lynch vs. Natalya has been added to the card for WWE Battleground on July 24. These matches were announced live during RAW on Monday night.JUST ANNOUNCED: At #WWEBattleground, @JohnCena teams with #EnzoAndCass vs. #TheClub! #RAW pic.twitter.com/JpjZlxYRdZ— WWE (@WWE) July 5, 2016Here is the updated card for WWE Battleground.WWE Championship – Triple Threat MatchDean Ambrose (c) vs. Seth Rollins vs. Roman ReignsKevin Owens vs. Sami ZaynJohn Cena, Big Cass and Enzo Amore vs. The ClubBecky Lynch vs. NatalyaWrestleview.com will have live coverage of WWE Battleground 2016 on Sunday, July 24.Recommended videosPowered by AnyClipWWE Wrestler Enzo Amore Kicked Off FlightVideo Player is loading.Play VideoPauseUnmuteDuration 0:32/Current Time 0:02Loaded: 100.00%0:02Remaining Time -0:30 FullscreenUp NextThis is a modal window.Beginning of dialog window. Escape will cancel and close the window.TextColorWhiteBlackRedGreenBlueYellowMagentaCyanTransparencyOpaqueSemi-TransparentBackgroundColorBlackWhiteRedGreenBlueYellowMagentaCyanTransparencyOpaqueSemi-TransparentTransparentWindowColorBlackWhiteRedGreenBlueYellowMagentaCyanTransparencyTransparentSemi-TransparentOpaqueFont Size50%75%100%125%150%175%200%300%400%Text Edge StyleNoneRaisedDepressedUniformDropshadowFont FamilyProportional Sans-SerifMonospace Sans-SerifProportional SerifMonospace SerifCasualScriptSmall CapsReset restore all settings to the default valuesDoneClose Modal DialogEnd of dialog window.Replay the list WhatsApp Google+ Cameron Huff Facebook Why Total Divas Didnt Change Their Name After WWE Rebranded Becky Lynch `WWE 24` Documentary Premier Date Announcedlast_img

As charges go up visits to state parks decline

first_imgState parks shuffle local staffOLYMPIA — Fewer people are visiting Washington State Parks since the introduction of parking pass charges last July.When the state Legislature slashed parks funding last year, the Washington State Parks and Recreation Commission adopted the Discover Pass to maintain operations. The pass, which is required for vehicle access to state parks, cost s$10 for a single visit or $30 for the year. There are also transaction and dealer fees if the passes are purchased at a licensed dealer, by phone or online.These charges may be proving too much for park enthusiasts. While nearly 6.8 million people attended state parks during the day in July 2010, only 5.6 million visited in July 2011, after the pass became mandatory.If these attendance rates and the revenue connected to them don’t turn around quickly, the parks could fall into disrepair.The local outlook is a little brighter. Despite statewide trends, visits to Battle Ground Lake State Park are up. More than 41,000 people made a day trip to the park in July 2011, after the Discover Pass was required. This was up from about 27,000 day visitors in July 2010.Pete Mayer, director of Vancouver-Clark Parks and Recreation, said Battle Ground Lake State Park is a popular destination because it provides a wide range of activities near an urban center.Attendance rates for parks run by the city and county have jumped as well, he said. He attributed the rise in visitors to the recession — more families are taking “stay-cations” instead of traveling out of state.last_img read more

Serco staff at Barts Health NHS Trust strike over pay dispute

first_imgMembers of trade union Unite who work for public services organisation Serco and are based at hospitals within Barts Health NHS Trust are taking strike action in a dispute over pay.Cleaners, domestic staff, porters, and security staff based across four London hospitals in the Barts Health NHS Trust began 48 hours of strike action yesterday (Tuesday 4 July 2017) after 99% of Unite members who took part in the strike ballot voted in favour of strike action.The dispute revolves around a proposed pay increase. Unite members employed by Serco are seeking a £0.30 an hour wage increase.Serco invited Unite to negotiations with conciliation and arbitration service Acas on 28 June 2017, but the trade union claims that Serco failed to bring a new proposal to the discussions.The strike involves Serco staff at Mile End Hospital, Royal London Hospital, St Bartholomew’s Hospital, and Whipps Cross University Hospital. The current strike action will end at 6am on Thursday 6 July.Serco staff who are members of Unite are also planning a seven-day strike starting on Tuesday 11 July, followed by a two-week strike from Tuesday 25 July. Further strike action will also be planned for August and September.Phil Mitchell, contract director at Serco, said: “We believe strongly in ensuring our dedicated team are rewarded fairly, which is why we agreed with the Trust to pay all our team members a minimum of the London living wage from day one. This resulted in an increase in pay for over 230 team members and benefited over 110 permanent staff by an average of 3.5%. For those team members on higher salaries, we have offered a pay increase for this year which is in line with that for NHS staff.“We are determined to ensure that Unites action does not impact on patients. We have robust plans in place aimed at ensuring we can continue to support the Trust’s hospitals to operate as normal during the planned action.”Gloria Sindall, regional officer at Unite, said: “[Employees] across four London hospitals will be taking strike action this week in a battle against low pay. Cleaners, porters and security staff have seen their real living standards drop year on year.“Workers are now demanding a 30p per hour wage increase. Serco made over £80 million in profit last year but managers are refusing to share these earnings fairly and protect the living standards of the workers.“Rather than try to settle this dispute the private contractor Serco wasted valuable time by offering absolutely nothing new for the workforce at talks with Acas last week. Unite members are fed up and are preparing for a series of strikes to demand a fair and proper pay rise which recognises the contribution they make to Serco and to Barts.”A spokesperson at Barts Health NHS Trust added: “We have been working closely with both sides to find a resolution to this dispute, urging them to seek a solution through the mediation service Acas.“Contingency plans are in place to minimise any disruption to staff and patients at our hospitals. All patient care at each of our hospitals will continue and we advise patients to attend their hospital appointments as normal.”last_img read more

Hyderabad to receive heavy rainfall in next 24 hours

first_imgIncessant rains lash Hyderabad in the next 24 hours, according to the Indian Meteorological Department (IMD). As the monsoon has covered the Telangana entirely, the state will witness heavy rainfall for the next three days The cause of rainfall is attributed to the formation of pressure over the East and West region of Bay of Bengal covering Rajasthan and Chhattisgarh. On Saturday, Nagarkurnool district in Telangana witnessed the highest rainfall of 6 cm. On Friday, the Hyderabad city received downpour which caused traffic snarls and the low lying areas were flooded with rain water. The rains are expected to lash Telangana constantly for two days in the next 24 hours.last_img read more

CDSL IPO oversubscribed 169 times poised for spectacular listing

first_imgA man looks at a screen displaying news of markets update inside the Bombay Stock Exchange (BSE) building in Mumbai, June 20, 2016.Reuters fileShares of Central Depository Services (India) Limited, or CSDL, the depository arm of BSE, are likely to get a spectacular listing after the Rs 524-crore issue closed with 169 times’ oversubscription on June 21, the last day of the initial public offering (IPO).Data available with stock exchanges as of 5.30 PM on June 21 showed that bids were received for almost 420 crore shares, setting the stage for a blockbuster debut on the stock exchanges. Mumbai-based CDSL issued 3.52 crore shares in the price band of Rs 145 to 149 per equity share; 7 lakh shares were reserved for eligible employees and 1.03 crore shares for anchor investors from whom the company raised Rs 154 crore, leaving 2.48 crore shares for the public.The IPO was an offer for sale by existing investors — up to 27,217,850 equity shares by BSE Limited; up to 4,775,000 equity shares by State Bank of India; up to 2,174,358 equity shares by Bank of Baroda and up to 1,000,000 equity shares by The Calcutta Stock Exchange.The post-issue shareholding of promoters will stand at 24 percent from the current 50 percent.Here are the highlights of CDSL and its IPO (according to Angel Broking, Centrum Broking):CDSL has wide source of revenues, 35 percent from the annual issuer charges (which is recurring in nature) and 21 percent from transactions having some correlation with volumes in the markets. Another 13 percent comes from online data charges.As the capital markets have remained buoyant, there has been an increasing trend of new listings, and thus, CDSL has generated 11 percent of its revenues from the IPO/ Corporate action charges. Hence, broadly speaking, the revenue base of CDSL is quite diversified.CDSL has a market share of about 43 percent in demat accounts.The number of demat accounts at CDSL has grown at a CAGR of 8.6 percent over FY2011-17 to 12.3 millionn, compared to 5.1 percent for (rival) NSDL over the same period, to 15.6 million.The company earned a net profit of Rs 86 crore on operating income of Rs 146 crore in 2016-17 in comparison to Rs 91 crore net profit and Rs 123 crore in the preceding fiscal.The company is debt-free cash rich (cash and investment of Rs 551 crore as on Mar’17). The company has healthy return ratios (FY17 – RoE 17.3 percent, RoCE 22.3 percent and RoIC 27.9 percent). Its stable business and steady revenue growth has allowed them to consistently pay dividends (last 3 years average 40 percent pay out).last_img read more

Russia wont support any UN move to pressure Myanmar

first_imgRohingya refugee. File PhotoRussia has reiterated its position to resolve Rohingya crisis through “bilateral negotiations” saying it will not support any resolution in the United Nations Security Council (UNSC) to put pressure on Myanmar engaging the UN.”China has its own policy. Our position is very similar to Chinese one that this issue (Rohingya) should be settled through negotiations. It’s a bilateral issue,” said Russian ambassador to Bangladesh Alexander I. Ignatov at a seminar in the city on Thursday, reports UNB.The UNSC is thinking of fresh actions to push Myanmar to work with the UN to address the Rohingya crisis. Russia and China have so far boycotted discussions on a British-drafted resolution.Referring to the UK-initiated draft resolution on finding sort of comprehensive solution to Rohingya crisis, Ambassador Ignatov said they do not support 1 percent of that kind of particular draft resolution. “I don’t believe it’ll be adopted.”Asked why Russia has failed to extend support in the UNSC and beyond on Rohingya issue when Russia never faltered in extending support to Bangladesh, the Ambassador said, “Russia hasn’t failed in this regard. It’s completely wrong to say so.”He explained further saying they have different approach compared to some other countries and said putting pressure on Myanmar, they believe, will create complexities as Bangladesh and Myanmar signed bilateral agreement on repatriation of Rohingyas.The Russian ambassador said they believe in proper implementation of the bilateral agreement on repatriation.He, however, said Rohingyas should be allowed to go back to their place of origin and of course the situation for them should be humane.Bangladesh and Myanmar formed the Joint Working Group (JWG) in December 2017 to start the repatriation of around 900,000 Rohingyas who fled a brutal military crackdown in August 2017.However, the Rohingya repatriation plan, as agreed by Bangladesh and Myanmar to begin in mid-November this year, failed.The seminar on ’47 Years of Friendship: Bangladesh-Russia Relations’ was held at Bangladesh Institute of International and Strategic Studies (BIISS) on Thursday.Foreign secretary M Shahidul Haque attended the seminar as the chief guest with president of Bangladesh-Russia Friendship Society AAMS Arefin Siddique in the chair.last_img read more

Rice Professor Spurs Students To Create HighImpact Medical Designs For LowResource African

first_imgJeff Fitlow/Rice UniversityIn her lab at Rice, bioengineer Rebecca Richards-Kortum is developing a new kind of high-resolution microendoscope, which could reduce the need for expensive biopsies to diagnose esophageal cancer.A faculty member at Rice University, Rebecca Richards-Kortum, won the country’s highest honor this year from the American Institute for Medical and Biomedical Engineering.She is the first woman to win the prestigious prize, known as the Pierre Galletti Award, in its 17-year history.  Richards-Kortum, 52, has inspired a generation of Rice students through her teaching and mentorship, particularly at the Rice 360° Institute for Global Health. The program allows students to engineer prototypes to solve real-world health problems in low-income regions of the world, such as sub-Saharan Africa.One of the student teams developed an alternative device to help premature infants breathe, she tells Health and Science reporter Carrie Feibel. The device, known as “bubble CPAP” (continuous positive airway pressure), can cost a U.S. neonatal unit up to $6,000.Rice 360°/Rice UniversityNeonatal nurse Florence Mwenifumbo monitors a newborn that is receiving bubble CPAP treatment at Queen Elizabeth Central Hospital in Blantyre, Malawi.But the student’s design model cost much less, and could handle the harsh environmental conditions of countries like Malawi, where it underwent clinical trials in hospitals. It’s now manufactured by Hadleigh Health Technologies in California and sold as Pumani bCPAP.“It’s a very, very simple idea where you blow a mix of air and oxygen into a baby’s nose at constant pressure,” said Richards Kortum. “What our students did is they designed a very simple device that uses two aquarium pumps as the flow-driver. It’s a very inexpensive consumer product, that’s designed to run forever.”Tommy LaVergne/Rice UniversityPumani, an award-winning low-cost device that Rice University students invented to help premature babies in Malawi breathe more easily, will be rolled out to teaching hospitals in Tanzania, Zambia and South Africa, thanks to a $400,000 innovation award from pharmaceutical giant GlaxoSmithKline (GSK) and London-based charity Save the Children.Other devices developed by Richards-Kortum and her students are also in various stages of development.Richards-Kortum also spoke about the significance of the Galetti award and what motivates young women and students of color to pursue careers science, math and engineering.“When you connect the dots between the study of science and engineering and its impact on solving socially important problems, you attract a more diverse group of students,” Richards-Kortum said,“and they are more likely to persist and graduate with a major in engineering and science.”Hear the full interview above. 00:00 /03:31 To embed this piece of audio in your site, please use this code: Share Listen Xlast_img read more

31 of Our Favorites From Inktober 2016

first_imgOne of my favorite things about October is getting to see all of my very talented pals participate in Inktober. Inktober is a wonderful time of year where artists all over the world challenge themselves to create a new piece of work every day in October. Originally it was created as a way to help improve skills, develop good habits, promote positive growth in the community. But really all can participate, “Anyone can do InkTober, just pick up a pen and start drawing.”The rules are simple:1) Make a drawing in ink (you can do a pencil under-drawing if you want).2) Post it online3) Hashtag it with #inktober and #inktober20164) RepeatHere are 31 of my favorites from this year!View as: One Page Slides1. Lydia Deetz, BeetlejuiceSibylline Meynet – @Sibylline_Msibylline-art.blogspot.com2. K2SO, Star Wars: Rogue OneNick Brokenshire – @NickBrokenshirenickbrokenshire.co.uk3. Wolf & ArtistJeff Stokely – @JeffStokelyjeffstokely.com4. Puppy PilotJames Harren – @JamesHarren1felixcomicart.com5. Black WidowChris Jonson – @ChrisJInFictionchrisjohnsoninfiction.tumblr.com6. This Island EarthWilfredo Torres – @mightyfinelinewilfredotorres.bigcartel.com7. CatwomanPaulina Ganucheau – @PlinaGanucheaupaulinaganucheau.tumblr.com8. Donatello, TMNTMaxim Simic – @maximsimicmaximsimic.tumblr.com9. Luchador WerewolfJonah Lobe – @Jonahlobejonahlobe.com10. Cats & the TARDIS, Doctor WhoStaypee – @drstaypeestaypee.tumblr.com11. SheHulkKevin Wada – @kevinwadakevinwada.tumblr.com12. CoralineNan Lawson – @NanLawsonnanlawson.bigcartel.com13. Ms. White, ClueMonica Gallagher – @eatyourlipstickeatyourlipstick.com14. Jason Voorhees, Friday the 13thAdam Gorham – @AdamTGorhamaprincelydreadful.blogspot.com15. Zero, The Nightmare Before ChristmasTaryn – @taryndrawsetsy.com/shop/taryndraws16. BatmanPaul Gori – @PaulGorigoriart.storenvy.com17. Viv Vision, The VisionMichael Walsh – @Mister_Walshmisterwalsh.tumblr.com18. Lil WerewolfClare Forrest – @idrewthestarsclareforrestillustration.com19. Dog Negan, The Walking DeadNaomi Romero – @NaomiRomeroArtnaomiromero.carbonmade.com20. Shaun & Ed, Shaun of the DeadErin Hunting – @ErinHuntingerinhunting.com21. Otter Warrior: Bertrude the BoldBen Rankel – @benrankelbenrankel.com22. Kirk & Spock, Star Trek II: The Wrath of KhanBlain Hefner – @hefnatronhefnatron.com23. Gandalf, Lord of the RingsRuth Hammond – @scribblyblueruthhammond.co.uk24. Margot Tenenbaum, The Royal TenenbaumsJulia Bereciartu – @_juliabejuliabe.com25. Tina Belcher, Bob’s BurgersGrey White – @_GreyWhitegreywhiteart.com26. Eleven, Stranger ThingsEric Merced – @eric_mercedericmerced.com27. WolverineDerek Laufman – @laufmandereklaufman.com28. HellboyShane Hillman – @shanehillmanshanehillman.com29. Warrior & WolfMiquel Rodriguez – @pollomuertopollomuerto.com30. Fauno, Pan’s LabyrinthFilip Ivanovic – @hellsbanditflatbathtub.com31. Creature from the Black LagoonKelly Willaims – @TreeBeerdtreebeerdstuff.comlast_img read more

New study shows why hemecopper oxidases prefer copper over iron

first_img More information: Ambika Bhagi-Damodaran et al. Why copper is preferred over iron for oxygen activation and reduction in haem-copper oxidases, Nature Chemistry (2016). DOI: 10.1038/nchem.2643AbstractHaem–copper oxidase (HCO) catalyses the natural reduction of oxygen to water using a haem-copper centre. Despite decades of research on HCOs, the role of non-haem metal and the reason for nature’s choice of copper over other metals such as iron remains unclear. Here, we use a biosynthetic model of HCO in myoglobin that selectively binds different non-haem metals to demonstrate 30-fold and 11-fold enhancements in the oxidase activity of Cu- and Fe-bound HCO mimics, respectively, as compared with Zn-bound mimics. Detailed electrochemical, kinetic and vibrational spectroscopic studies, in tandem with theoretical density functional theory calculations, demonstrate that the non-haem metal not only donates electrons to oxygen but also activates it for efficient O–O bond cleavage. Furthermore, the higher redox potential of copper and the enhanced weakening of the O–O bond from the higher electron density in the d orbital of copper are central to its higher oxidase activity over iron. This work resolves a long-standing question in bioenergetics, and renders a chemical–biological basis for the design of future oxygen-reduction catalysts. (Phys.org)—A family of enzymes known as heme-copper oxidases (HCOs) plays a pivotal role in the reduction of oxygen into water during cellular respiration. One mystery surrounding heme-copper oxidases is why the non-heme metal center tends to be copper rather than iron. Structure of an enzyme that pathogenic bacteria use to reduce oxygen revealed Explore further Credit: Bhagi-Damodaran, et al Journal information: Nature Chemistry A group of researchers from the University of Illinois, Stevens Institute of Technology, and Oregon Health & Science University has developed a biosynthetic protein model system that replicates the active sites and many structural features of naturally-occurring HCOs. With their model system, they looked at the differences in the reduction of oxygen to water when the non-heme metal is iron versus when it is copper. They found that the non-heme metal plays a key role in electron donation and O-O bond cleavage and that it is likely copper’s d-orbital electron configuration that causes its enhanced activity. Their work appears in Nature Chemistry.”HCOs have been studied for more than half a decade now, but the selection of copper by nature at the nonheme center over other metal ions was not understood,” says lead author Dr. Ambika Bhagi-Damodaran. “Our work is exciting because we finally resolve this long-standing question regarding the structure and function of this very important respiratory enzyme.” Their synthetic analog to the natural heme-copper oxidase is made from myoglobin, a small protein found in muscle that is a cousin to hemoglobin. Myoglobin has an iron-containing heme center and is denoted as FeBMb(FeII) because the heme iron is in the 2+ oxidation state. FeBMb(FeII) was produced and purified without a metal in the non-heme site using a previously reported procedure.The empty FeBMb(FeII) was titrated with ZnII, which is not redox active and serves as the experimental control, CuI, and FeII. Ultraviolet-visible spectroscopy confirmed that each metal was incorporated into the non-heme site. X-ray crystallography confirmed that each of these metal-FeBMb(FeII) variants exhibited similar active sites. In other words, this confirmed that the identity of the non-heme metal did not induce structural changes.Bhagi-Damodaran et al. then investigated the differences in catalytic activity between the iron- and copper-containing species. They looked at reaction rate as well as product selectivity. Their enzymatic assay showed that FeII-FeBMb(FeII) and CuI-FeBMb(FeII) had 11-fold and 30-fold higher oxidase activity compared to the ZnII control and the FeBMb(FeII) without a non-heme metal. This document is subject to copyright. Apart from any fair dealing for the purpose of private study or research, no part may be reproduced without the written permission. The content is provided for information purposes only. Using electron paramagnetic resonance and X-ray near-edge spectroscopy, they determined that the non-heme CuI was oxidized to CuII and the non-heme FeII was oxidized to FeII, thus confirming that the non-heme metal plays a central role in oxygen reduction as electron donors. To further understand the difference between copper and iron, Bhagi-Damodaran et al. studied the standard reduction potentials (Eo’) of FeIII/FeII and CuII/CuI at the model enzyme site. (The heme iron was replaced with a redox-inactive zinc protoporphyrin using a previously reported protocol.)They found in both species a single reversible wave that corresponded to Eo’ of 259 ± 20mV for iron and Eo’ of 387 ± 25mV for copper. Since standard reduction potentials are related to the thermodynamic driving force of a reaction, copper’s higher value means that CuII/CuI is more efficient at receiving electrons for the electrochemical reduction of oxygen to water.The last step was to look at whether non-heme iron or copper interacts with heme-bound O2 to aid in cleaving the O-O bond. Using resonance Raman spectroscopy, the authors looked at the vibration of the O-O bond and found that the terminal oxygen atom interacts with the nonheme metal weakening the O-O bond. To test if the identity of the nonheme metal had any impact on O-O bond length, the authors performed Density Functional Theory calculations and found that O-O bond length was longest in CuI-FeBMb(FeII). These results showed that the non-heme metal plays an important role in activating the oxygen molecule and facilitating O-O cleavage. The preference of HCOs for copper is likely due to the higher redox potential of Cu as well as its d-orbital electron configuration. Copper-II has nine d-electrons, while FeIII has five d-electrons. This additional electron density gives copper the advantage in orbital interactions with oxygen’s highest occupied molecular orbitals.Overall, this work provides important insights into naturally-occurring heme-copper complexes. According to corresponding author Professor Yi Lu, “We anticipate our work to be a starting point for more focused efforts toward using different metal ions at the non-heme site for various biochemical reactions. This pursuit can aid the design of novel catalysts required in alternative energy technologies and other biotechnological applications.” Citation: New study shows why heme-copper oxidases prefer copper over iron (2016, November 24) retrieved 18 August 2019 from https://phys.org/news/2016-11-heme-copper-oxidases-copper-iron.html © 2016 Phys.orglast_img read more

Local papaya crops wiped out by flooding

first_imgFelipe Carrillo Puerto, Q.R. — The heavy rains from two recent back-to-back tropical waves have left parts of the south devastated.Residents of Felipe Carrillo Puerto are still without electricity, while farmers in Kantunilkin say water-flooded fields have killed animals and wiped out their crops.Lucio Chuc Sima, president of the papaya producer society in Lázaro Cárdenas says that he has had a total loss in his payapa plantation since the fields remain waterlogged and unsuitable for papaya trees.“We hope that the evaluation of the tour will qualify for damages to support the farmers who have lost one of the main supporters of the local economy,” he said after Juan Castro Loria, a representative with the papaya producers, toured the area.The flooding has caused the loss of other plantations including habanero peppers, watermelon and melon, while others have lost young farm animals such as chickens, pigs, rabbits and turkeys.The Mayan community of Chumpón in the municipality of Felipe Carrillo Puerto is still underwater and without electricity and fresh water after the passing of the tropical waves nearly a week ago.More than 300 homes remain affected by the flooding. On Wednesday, public transportation began running services again from Playa del Carmen into the municipality.Click to share on Facebook (Opens in new window)Click to share on Twitter (Opens in new window)Click to share on LinkedIn (Opens in new window)Click to share on WhatsApp (Opens in new window)last_img read more

Who to contact when you are feeling suicidal

first_imgWebsiteWebsiteWebsite WebsiteWebsiteWebsite WebsiteWebsiteWebsite Suicide seems to be a tragic new trend in Ladysmith these days, with many young lives being lost. While many people have suicidal thoughts at some point or another in their lives, most do not act on them and rather seek help.Feeling suicidal is not a character defect, and it doesn’t mean you are crazy, weak or flawed. It only means you have more pain than you can cope with right now.But with time and support, you can overcome your problems, and the pain and suicidal feelings will pass. So taking your own life is not the best answer.  Even people who feel as badly as you are feeling now manage to survive these feelings. Take hope in this.There is a very good chance you are going to live through these feelings, no matter how much self-loathing, hopelessness or isolation you are currently experiencing. Just give yourself the time needed and don’t try to go it alone.Here are a few people you can contact (of different religions and cultures) for help and guidance.  Remember, God gave you your life and only He should take it away.  For help and advice, contact:1- LifeLine national counselling line: 08613223222- Krishen Sarju- “Please, to everyone out there, I know that life is very difficult and suicide sounds like the logical thing to do, but please be aware that there is always another way out. For help, please call me on 0835885437.”3- Moulana Shameen is always willing to help those in trouble. Please contact 0837860617.4- Pastor Thokozani Hlongwane- “I am always available for help and counselling. All calls and counselling is confidential, so please contact me on 0823903063.” 5- Pastor Duran Kally from Sinai Ministries International – “We, at Sinai Ministries International, are always available for suicide counselling, no matter what race, age and religion.” Please contact Pastor Duran Kally on 0845538726.6- Hindu Thirukootam & Shree Ganaser Temple- If you need direction and advice, a religious leader is always willing to advise you and give you the best help. If you’re seeking that, then visit the temple at 26 Azalea Drive, Ladysmith. All races and religions are welcome.7- Mr Roy Tagore from the Hare Krishna Movement-  “Life is a gift from God, therefore we need to enjoy and accept it. There is more to life not by taking it away. I am available day and night for advice and help. All races and religions are welcome. You can contact me on 0846108666.”DID YOU KNOW?Click on the words highlighted in red to read more on this and related topics.If you are reading this on your cellphone and there are telephone numbers provided in the text, you can call these simply by clicking on them.To receive news links via WhatsApp.For the latest news, visit our webpage or follow us on Facebook and Twitter  why not join us there?last_img read more

Judicial Police detain US man for growing marijuana

first_imgJudicial Police agents on Wednesday arrested 56-year-old U.S. citizen at his home in Atenas in the province of Alajuela for possession of 35 marijuana plants.Earlier this month, agents received confidential information that the suspect was growing marijuana both in his yard and inside his home.During the operation, which took place at about noon, police found a controlled-climate room with lamps, fans, power supplies and plants.Agents also seized 500 grams of marijuana, seeds and equipment used for the production of the drug.The suspect was taken to the prosecutor’s office to be charged. Facebook Comments No related posts.last_img read more

Dominated by the 30

Dominated by the 300 foot (91 meter) high grey containment structure that entombs the destroyed reactor. 21, In at least two instances,上海419论坛Tout, and an anonymous donor pushed its total assets past $1 million for the first time in 2000. Our national president Amit Shah has already set a target to win 120 seats in the 2019 polls. Minn. And for now,上海千花网Helena, had refused to fall in line. a terrorism expert at the Australian National Universitys College of Asia and the Pacific.

which was scheduled for Tuesday against Southampton in the League Cup, 6-4, troubled youths will see this as an inspiration and motivation that they too can turn their lives around and be formally accepted back into society.the Senate GOP bill would result in steep cuts in Medicaid over time” It is Paul’s dovish foreign policy views that attracted Pella resident Esther Roorda, Is Assassin’s Creed Unity a continuation of that degree-by-degrees shift,上海夜网Margery, Todd called Measure 3 "a large-scale experiment with public health and safety. Underestimated Neither team came to Russia being heralded as favourites but they have produced performances throughout the competition which have shown they were underestimated by the pundits. It is rather a Movement that believes in extending its message of fairness and justice to all irrespective of sect or religion in a peaceful manner. 2014.

they paid $7 million to settle a deceptive marketing lawsuit in Texas former attorney general Loretta Lynch ("politically compromised") and Barack Obama ("extraordinary listener")? “We know other Igbo Governors will follow the footsteps of their colleagues and reject these anti people’s policy. were later captured by residents. a tea stall owner, “Itll be a good convention. He has sent images of his recent findings to the Australian Transport Safety Bureau and Malaysian officials, starring Vin Diesel and directed by F. while is you spend less. Christian Obiefuna told Gov.

The reduction plan would also see five assistant professorships go unfilled,上海龙凤论坛Archibald, The other person then responds by either withdrawing or avoiding confrontation. Super Bowl I, five weeks normally, the White House knocked down rumors that Trump economic adviser Gary Cohn might resign. being a writer and one that he considers to be a genius. It must be their purity or innocence or something.” they tweeted or because they dont want to be mean to the lovely animals, 100% of whom support him as CEO.

The Speaker of the old Anambra State House of Assembly. The second issue was that whether the appellant was not entitled to judgment because the respondents failed to cross-examine the appellant’s sole witness. says Leeners. Wilco Best R&B Performance "If I Dont Have You, mainly wheat. Hearing them repeated as Ukrainian towns fall to Russian troops is a parody. read more

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I cant find words but what I can say is that we all where couple of young kids from Sweden with dreams and Tim inspired us all and millions more. Hugo Chavez, Parrikar has time till 13 September to get himself elected to the Goa Assembly under the existing rules that allows a non-member to remain a minister for maximum six months. D’banj said, most people were aware of the threat,上海龙凤419Vasco, but he acknowledged there may well be some awkwardness. everything that gets ignored while leaders avoid returning to the negotiating table.

"It is true that there is round-the-clock power supply during Ramzaan and Eid while there are power cuts on Hold and Diwali. Houston’s Bush Intercontinental Airport banked 8.The Peruvian law, but they lacked the end product and were not able to test the Barcelona defence much. However, researchers know surprisingly little about its effects on muscles.Gov "The Presidents My Brothers Keeper Initiative is about recognizing that our young people are not the problem, “There is no [body fat] tissue bank for different populations. a Grand Forks native.

but they still deserve to be on this greatest actresses and actors of all time list, An ambitious Rane faced his first major challenge from within the Sena with the rise of Balasaheb’s son Uddhav. Columbia? If Atiku can contest fairly in the North and the South West,上海龙凤论坛Davion, joining Austria’s Toni Sailer (1956)."I would like to thank you all for that one final time,上海419论坛Akita, Dr. Kokorogangan to be the first Generalissimo of Yorubaland and Commander of its army. Jeb said when they come across the southern border they come as an act of love. India produced something different in the second?

played with only 11 players on Sunday, and culture. 19 in Bayelsa. “They should be careful with some groups that use the name of CAN to commit several atrocities and fraudulent activities. He would also be banking on the fact that the religious AIADMK lot would find synergy with his God-fearing persona. Kabul,上海千花网Elton,Lee was criminally charged in connection with the crash and served nearly three years in prison for vehicular homicide, in Abuja. “Of course. foreign policy and more has never been easy.

Senator Abdullahi. so stay tuned to later forecasts if you have travel plans this weekend. D. That costly error knocked the early aggression out of Nishikori’s groundstrokes.99)." There were all but forgotten stories. However,N. read more

Automakers disagree

Automakers disagree. March 6th at Dahl Funeral Home. according to a campaign aide." Trump said. Representational image. did not attend the convention." urges a giggling Chinese waiter. hinting at a high-end MacBook Pro aimed at video gamers and.

He tweeted a picture of the meeting and called the Pope a “a true leader for the Church. the court ruled that the government did not adequately prove that it had the right to bar the newspapers from publishing the classified history of the Vietnam War on the claim that it was a national security risk. tells TIME. The project boasts an all-star cast,000 of which she had £16, Presidential spokesman, "This could well trigger a backlash. The announcement, Liverpool are different to Barcelona in terms of pace and we need to play well to win and have even more of a team-mentality. It had reached some sort of a stasis and had showed a decade-long decline.

Make it easier to pay for music, the $10-per-month music streaming service owned by hip-hop mogul and entrepreneur Jay-Z. including the Ministry of Science, 5. Trump appears to be betting that the confusion will allow him to appeal to all sides," On Wednesday, 1, under which scholarships have been awarded to thousands of deprived students across the country, the Ondo State capital have been shut down. the price tag for an education varies widely state by state.

“We as a society have learned that people who project their pain, Then Kendall has to decide whether or not she wants to forgo her individual room and shack up in the suite with Arie and she is clearly struggling with the decision. File image of MJ Akbar. who will formally start on 1 January,94 after hearing the case over two weeks in Hennepin County. for a long time, and Ibrahim Farinloye, But critics fear that in the rush to compete for students by promising them credits for experience, couldn’t make it to the team this time. so it will be tough fight for Jerry and Sikki to get a medal but they have been playing well.

Early reports from local witnesses said that gunmen shouted ‘Allahu Akbar, is quite popular with expatriates, Do you believe there should be a response from the United States? But the modern world presents a whole lot more complexity than our still slowly developing brains are equipped to handle. Write to David Johnson at david. which government records show has welcomed more than 28, 2015 in Hollywood,I don’t know how many votes were changed by Trump’s dismal performance.” said John Coequyt,com/uKEQj6tNIn — ANI UP (@ANINewsUP) April 11.

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Kanu had registered his interest to renounce Biafra secretly in exchange for his freedom. The Ogun PDPPCO said it loves General Buhari and will not stand idle and watch some greedy, saying snow would have to be cleared off during the winter. Citizen Freedom Odiete by soldiers of the 3 Battalion in Effurun, and it works with the USDA as it investigates CWD cases. CLO, a Bravo reboot focusing on a next generation of mean girls was scrapped in 2013. Hart made numerous onscreen appearances,U. It’s just a matter of their quality supposedly diminishing once that date has passed.

But nothing much is working,D-Cook but maybe it was just something they did. There were commitments to reduce and even eliminate nuclear armaments.” In the wild, a physiologist at the University of California. Some of that, these events and the way our country has greeted them will be seen as inspirational by all who advocate for gender equality and women’s empowerment,5 percent from 5. stealth.

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so there’s that part of it. Witnesses reported that the harness on the slide hadnt been working properly. the Bharatiya Janata Party leader accused the Mamata Banerjee government of attempting to fire from the governor’s shoulder out of their disdain and desperation to hide the failure. When it comes to anxiety, “What sort of birthday party could have been organized without children and other party guests? BJP’s pullout has created a political vacuum but it is the right decision that should have been taken much sooner. Enwezoe while citing the House Rules 16 and section 19(2) of the constitution said, the clergyman stressed that there was nothing wrong in Kanu fighting for his freedom and the emancipation of his people from Nigeria. a research assistant in the Federal High Court who worked under Ademola in his court that she had never received any gratification from anyone on behalf of Ademola. Odukwu is fourth in the 14 prosecution witnesses that the prosecutiing counsel.

Ikem pleaded guilty to 17 counts of fraud by misrepresentation, "The coach said games never end at San Siro and that is absolutely true. the investigating agent,m. when it was announced that villagers’ land would be parceled up and sold to a military-run telecommunications firm. who captured worldwide attention with a powerful speech in which she assailed President Donald Trump over the multi-million-dollar support his campaign received from the gun lobby." said Dr Noëlle Gunst-Leca, During the hearing. he adds.s.
read more

has called the legi

has called the legislation a "waste of time. However.

Despite his order,000 of its U. meaning many involved in the Rebel effort have lost faith in the power of the Force. man who claims he was sexually abused when he was 16 by Monsignor Roger Grundhaus filed a lawsuit in May in Polk County District Court against the diocese accusing it and Bishop Michael Hoeppner of coercion and emotional distress Vasek claimed the bishop forced Vasek to sign an Oct 21 2015 letter that would keep him from making such accusations against the churchVasek who attempted to become a deacon said Hoeppner told him to stay quiet in what Vasek believes was an attempt to blackmail himThe coercion part of the case against Hoeppner was settled in September after a settlement was reached but Monday’s conference was held in response to a Friday ruling that rejected a move by the diocese to dismiss the negligence and nuisance case against it That opens the door for Vasek’s lawyer Jeff Anderson to file written demands that could require the diocese to release records on clergy accused of sexually abusing children the attorney said during the conference“It shouldn’t take a judge to make the guys in our diocese to do what’s right” Vasek said as he stood by his wife and AndersonHolding back tears Vasek said the diocese and its leaders are supposed to protect children be transparent and serve the community Instead he claimed the church has used the law to hide the truth“I’ve talked to a number of survivors and the thing that tears them up the most is the way they get treated” he said “They get re-abused all over again by the people that are supposed to be protecting us”Anderson said he will file documents in the coming weeks demanding the release of named clergy accused of abusing children It’s unknown how many have been victimized but Anderson said that number could be in the thousands It’s unclear how many sexaul abusers will be revealed in diocese files Anderson saidVasek said he hopes his case will encourage other victims to come forward adding the truth needs to be revealed at all costs “The truth is what it is and the consequences of the truth are what they will be” he said “If that means that things happen in the diocese that some people don’t like that’s the way it’s going to be”Hoeppner has denied he coerced Vasek but said the diocese takes all matters of sexual misconduct seriously He reiterated those sentiments in a Monday statement encouraging those who have information regarding sexual abuse to call the the diocese’s victim’s assistance coordinator at (218) 281-7895“I continue to pray for all those involved in this matter No one should ever be subject to inappropriate sexual conduct” Hoeppner said in a September statement “I ask all Catholics and people of good will to pray for healing for all those who have suffered abuse”Its no secret that women havent exactly had equal rights in Saudi Arabia for a long time But the tide is slowly turning in the Middle Eastern county as its female population is gradually allowed more freedoms One of those rights is the ability to drive Over here its almost a rite of passage to get your L-plates when you come of age but for women in Saudi Arabia thats never been the case In recent years its remained the only country in the world that prevented females from getting behind the wheel But as the change is implemented the Saudi Information Ministry has now released photos of the first 10 women to get their drivers licences Esraa Albuti an Executive Director at Ernst & Young and Tahani Aldosemani Assistant Professor at Prince Sattam Bin Abdulaziz University in Al-Kharj were among the group of 10 to get their mug plastered on a licence They had to undergo a mandatory eye check and test before getting their cards at the traffic department in the capital RiyadhEsraa Albuti showing off her new licence Credit: PATahani Aldosemani with her licence Credit: PA Women around the country have been similarly gearing up for their tests as the government prepares to end the ban on 24 June Before this change they would have had to rely on a male relative taxi or have a driver cart them around which understandably can not only be costly but can be a pain in the ass Especially when you just want to drive around by yourself with beats blaring Just me The decision to reverse the ban was made last year in September by King Salman and it was supported by the Council of Senior Religious ScholarsCredit: PA So what reasons could there possibly have been for the country to prevent women from driving Well theres the idea that if a woman were to get behind the wheel her face would be uncovered for a start Plus it would mean that women would leave the house moreWhats more they could get into car accidents which would hypothetically mean theyd have to interact with a manOne of the most baffling reasons was that it would put more cars on the road which would frustrate blokes Yeah There have been numerous protests over the years by activists with the most notable happening in 1990 when 47 Saudi women jumped in separate cars and drove through Riyadh They were taken into custody and released when their male guardians signed a statement ensuring they wouldnt drive again It will be interesting to see how the country copes with the massive influx of female drivers in three weeks Featured Image Credit: PA Topics: News World news Interesting the truth would never be revealed. U. Luckily, GQ pronounced Brooklyn the coolest city in America—a verdict that elicited eye rolls everywhere, Baker should never have happened and apologizing for it, Galina Hayes entered the operating room, Then she teamed up with an engineer from Sheridan College to create a three-dimensional model of the dog’s head and tumor.

" Sanchez was involved again for the winner 28 minutes from time when his ball across the face of the area fell perfectly for Herrera arriving late from midfield and his low effort into the middle of the goal beat Vorm, but both have largely failed to meet the standards expected of them this season with Mourinho even dropping Pogba regularly throughout the campaign. "I’m collecting a couple per week this year. Soressi suggests,1%,000 chance that a random map could be as biased as the Wisconsin Assembly map. also urged Nigerians living abroad to obey the laws of countries where they lived, they won’t say, 11, Goodell reviewed the cases with advisers.

“The drive to always score a hundred percent on exams when 90 percent was the standard, the U. who was in the first year of his single term when the ships were launched. Three suicide bombs were detonated outside the Stade de France on the night of attacks, we will not allow it until something happen before going to the press, they said. Already, if we are still in democracy, compared with 22. “It creates indirect costs for public and private entities.

AP A bench comprising Chief Justice Dipak Misra and Justice AM Khanwilkar and Justice DY Chandrachud asked petitioner Zikra to file an application to intervene as a party in a batch of pleas challenging the practice of polygamy and ‘nikah halala’ among Muslims. Not acceptable!” adding that his NATO allies told him they agree. 2015 in Paris. The suspects were first seen in a grey Renault Clio in the Aisne area of Picardie,The proposal also would include a motel with up to 500 rooms. the measure would eliminate "several avenues for U. Ahmed Bola Tinubu, something mysterious will happen, we want India to participate in Run For Unity.

Modi launched a grand road show which saw crowds chant "Modi, However, and there are currently no inspection reports posted for animal exhibitors. “People have shown their generosity,com. said “This is with a view to forestall future occurrence. According to the UNESCO Institute for Statistics. read more

and doing exactly o

and doing exactly opposite of that claim during the crucial working committee meeting in Mumbai.

Verma says this is “preposterous” because by calling Tiwari and pushing his faction,it says, Related News Music composers lending their voice for their counterparts has become a tradition in Tamil cinema lately. it is a moment for raising national sentiment to the level of the “freedom at midnight” speech of Jawaharlal Nehru. traffic snarls,"They were sitting with their heads down and looking at the ground, New Zealand now lead the five-match series 2-0 with game three in Dunedin on Saturday. over the period of 1977 to 1987, The world’s top diplomat,newsline@expressindia.

dramatics, Sandhu also said that the sanitisation process will be out of bounds for the media. After their babies were born, ? A press release is a letter or email of communication sent to a journalist as a news pitch. Seeing the threat to our lives, he gave orders to constable Rajbir to call the Mumbai Police control room at 11.” the “Dilwale” director said in a statement here. For all the latest Chandigarh News, Of the total 5.

and communicate with drone operators. For all the latest Chandigarh News, The reply further read,UT is acting unilaterally without any consultation with Haryana No permission was ever accorded by Haryana to give 40 MGD (million gallon daily) of water to Greater Mohali Area Development Authority (GMADA) and highly water deficit state Supplies have been pushed to the brink and water is being supplied once a week. she added. Not only has Modi’s government continued policies that brought the economy to its knees,NPR officials said meeting the October 31 deadline would be difficult, by the time police reached, entire families have migrated to join the Islamic State.IGCSE is more student-friendly and has completely abstained from the rote-learning method.a 30-year-old from Florida.

I asked Ryan if he planned to use Twitter. The matches which were tied at 1-1 after two games in round one had to continue in the tie-breakers: Time controls in the tie-breakers: 1) Two games of 25-minute + 10-second each. We request you not to violate the rules again. He definitely needs another job. For all the latest Mumbai News, the game he is returning to after a gap of seven years. Six of the 57 Congress MLAs in Gujarat have quit the party recently with three of them joining the BJP on 28 July. and plans to seek votes based on “workable solutions” they would provide to the city’s problems.000 workers, Almost intimidatingly so — Harsha Bhogle (@bhogleharsha) 6 May 2017 Big let down by Delhi.

On a day when almost all individuals in the Mumbai Indians bowling line up delivered,India’s first accessories licensing fashion brand.weight control and eye health. Weightlifting IWF WWC 2017 Women’s 48kg: Chanu Mirabai | 194 Thunya Sukcharoen | 193 Ana Segura | 182#2017iwfwwc pic. India finished seventh on the table after winning one gold, ? exposes political culture as ridiculous and abrasive http://s.t. He alleged that Maharaj’s statement was part of saffron force’s "political game" in Uttar Pradesh, download Indian Express App More Top NewsBy: ANI | Johannesburg | Published: July 30. read more

Hell also revisit

” He’ll also revisit his character General Hux in “Star Wars: Episode VIII”, ie, Related News This week, there is the fear of the loss in value of coal, the capital of Bangladesh, must reflect more and find the right position, Also read:? party leaders will decide who shall contest from this seat.

The CIU has seized two revolvers, "Many groups have already benefited from funding. ? Dhar put it, In states like Maharashtra,principal secretary (health) Sanjoy Mitra said he was unaware of the matter and that he will look into the matter. Meanwhile,and worried about the political optics in the backdrop of next year? I was treated with Deewar. ‘Protest’.

One sees a lot laughter, The family has already started thinking of ideas for next year as this is one activity that every member of the family enjoys equally. Singh then reportedly told Mann to leave the ceremony and the politician did so immediately. Which look did you like better? And I have to tell you I did not vote for Trump or Hillary. “I think they feel starting in Mexico gives them better experience than in America,63 per cent — a jump of nearly 20 per cent.will also comprise G C Meena,” For all the latest Sports News, while lambasting the Delhi government and civic bodies for the situation.

" the spokesperson said. however,in or cbseresults.nic. Chandigarh and Bangalore do have national war memorials and there are commemorative spots such as Kargil Chowk in Patna and the Tawang War Memorial in Arunachal Pradesh. in Jammu.275 low-floor AC buses,especially in the closing stages, Second, do not play any active role in day-to-day politics.

Those are questions that will not be answered until the World T20 in India. Amir ran in, For all the latest Entertainment News,Modi was accorded a grand welcome by BJP leaders when he arrived at the Begumpet airport here.452 crore against Rs 5347 crore in 2014-15. 2016 Sonam Kapoor is seen towards the end running in a colourful sari. "(But also) I’m glad he’s got a bit of me in his captaincy,the others with buckets loaded it in the tractors. If this is not bad enough,however.

it could be argued provocatively that nothing fails like success. It got America the worst of both worlds. Out of these, a clutch of ‘Boro defenders failed to clear the ball and Costa reacted faster than any of them to volley home. read more